Publications
:: Full CV
(undergraduate co-authors underlined)
21. J. D. Spence,
M. L. Lackie, N. A. Clayton, S. A. Toscano, M. A.
Farmer, E. Popova, and M. M. Olmstead. Syntheses, Structure, and Reactivity of
Acyclic Enetriyne and Enetetrayne Derivatives. Tetrahedron
Letters, 2014, 55, 1569-1572.
20. J. D. Spence,
A. C. Rios, M. A. Frost, C. M. McCutcheon, C. D.
Cox, S. Chavez, R. Fernandez, and B. F. Gherman. Syntheses, Thermal Reactivities and
Computational Studies of Aryl-Fused Quinoxalenediynes: Effect of Extended Benzannelation on
Bergman Cyclization Energetics. Journal of Organic Chemistry, 2012, 77, 10329-10339.
19. N. V. Korovina, M. L. Chang, T.
T. Nguyen, R. Fernandez, H. J. Walker, M. M. Olmstead, B. F.
Gherman and J. D. Spence. Syntheses
and Reactivity of Naphthalenyl-Substituted Arenediynes. Organic
Letters, 2011, 13, 3660-3663.
18. K. V. Lawson, A. C. Barton, and J. D. Spence.
Synthesis of Diazacalix[8]arene and Triazacalix[12]arene Methyl Ethers via
Intramolecular Aryl Amination. Org. Lett. 2009, 11,
895-898.
17. A. R. Urbach, C. J. Pursell, and J. D. Spence.
Supramolecular Chemistry: A Senior Capstone Course. J. Chem.
Ed. 2007, 84, 1785-1787.
16. J. D. Spence, A. E. Hargrove, H. L. Crampton,
and D. W. Thomas. Porphyrenediynes: Synthesis and
Cyclization of meso-Enediynylporphyrins. Tetrahedron Lett. 2007,
48, 725-728.
15. N. S. Mills, J. D. Spence and M. M. Bushey.
Capillary Electrophoresis Analysis of Substituted Benzoic Acids.
J. Chem. Ed. 2005, 82, 1226-1228.
14. J. D. Spence, E. D. Cline, D.
M. LLagostera and P. S. OToole. Synthesis and Bergman
Cyclization of a beta Extended Porphyrenediyne. Chem. Commun.
2004, 180-181.
13. T. D. Lash, M. A. Muckey, M. J. Hayes, D. Liu, J. D. Spence
and G. M. Ferrence. Regioselective Oxidation of Benzocarbaporphyrins
with Ferric Chloride: A Facile Synthesis of Bridged [18]Annulene Ketals
with Strong Absorptions in the Far Red and an Unexpected Halogenation
Reaction at the Interior Carbon Atom. J. Org. Chem. 2003,
68, 8558-8570.
12. J. D. Spence, A. E. Raymond and D. E. Norton.
Condensations of N-Arylhydroxylamines for the Preparation of
5,5-di-tert-butyl-2,2-dihydroxydiphenylamine. Tetrahedron
Letters 2003, 44, 849-851.
11. T. D. Lash, M. J. Hayes, J. D. Spence, M. A. Muckey, G. M.
Ferrence and L. F. Szczepura. Conjugated Macrocycles Related to the
Porphyrins. 21. Synthesis, Spectroscopy, Electrochemistry and
Structural Characterization of Carbaporphyrins. J. Org. Chem. 2002,
67, 4860-4874.
10. T. D. Lash, M. L. Thompson, T. M. Werner and J. D.
Spence. Synthesis of Novel Pyrrolic Compounds from Nitroarenes and Isocyanoacetates
Using a Phosphazene Superbase. Synlett 2000 (2),
213-216.
9. J. D. Spence and T. D. Lash. Porphyrins
with Exocyclic Rings. Part 14. Synthesis of
Tetraacenaphtho-porphyrins, a New Family of Highly Conjugated Porphyrins
with Record Breaking Long Wavelength Electronic Absorptions. J.
Org. Chem. 2000, 65,1530-1539.
8. D. K. Moss, J. D. Spence and M. H.
Nantz. Effects of Propargylic Substitution and Annelation on the
Cycloaromatization of a Bicyclo[7.3.1] Enediyne. J. Org. Chem.
1999, 64, 4339-4343.
7. T. D. Lash, J. L. Romanic, M. J. Hayes and J. D.
Spence. Towards Hydrocarbon Analogues of the Porphyrins:
Synthesis and Spectroscopic Characterization of the First
Dicarbaporphyrin. J. Chem. Soc., Chem. Commun. 1999,
819-820.
6. M. J. Hayes, J. D. Spence, and T. D. Lash. Facile
Oxidation of a Carbaporphyrin at the Internal Carbon Atom: Synthesis
of Novel Benzo[18]annulene Ketals. J. Chem. Soc., Chem. Commun.
1998, 2409-2410.
5. T. D. Lash, P. Chandrasekar, A. T.
Osuma, S. T. Chaney, and J. D. Spence. Porphyrins with Exocyclic
Rings. Part 13. Synthesis and Spectroscopic Characterization of
Highly Modified Porphyrin Chromophores with Fused Acenaphthylene or
Benzothiadiazole Rings. J. Org. Chem. 1998, 63,
8455-8469.
4. M. H. Nantz, D. K. Moss, J. D. Spence,
and M. M. Olmstead. Actuating Cycloaromatization of a Bicyclo[7.3.1]
Enediyne by Annelation, an Example of Inverse Dependence on Bridge
Hybridization. Angew. Chem. Int. Ed. Engl. 1998, 37,
470-473.
3. R. P. Balasubramaniam, D. K. Moss, J. K. Wyatt, J. D.
Spence, A. Gee, and M. H. Nantz. Methylation-Ring Opening of
3,3-Disubstituted 2,3-Epoxy Alcohols. Synthesis of Chiral Quaternary
Fragments for Assembly of Briaran Diterpenes. Tetrahedron 1997,
53, 7429-7444.
2. J. D. Spence, J. K. Wyatt, D. M.
Bender, D. K. Moss and M. H. Nantz. Stereogenic Propargylic Centers
Via Base-Mediated Terminal Allene Isomerization. J. Org. Chem.
1996, 61, 4014-4021.
1. J. D. Spence, L. E. Lowrie and M. H.
Nantz. Cyclobutene Formation Accompanying an Intramolecular Lewis
Acid-Promoted Spirocyclization of a Propargylic Silane. Tetrahedron
Letters 1995, 36, 5499-5502.
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